In said:
Explosive mixture in air has a very wide range of compositions 4-74%.
Acetylene is worse - 2.5 to 80 %.
Slightest spark will ignite it too.
Acetylene is much worse in that area.
You cannot even park it in a bunker unless it is well ventilated.
http://www-safety.deas.harvard.edu/services/hydrogen.html
Hydrogen at high pressure will diffuse through steel. And worst of all
a pure hydrogen flame is almost invisible in daylight (this is good in
one sense in that it doesn't radiatively couple).
Blue flames in general are mostly faintly visible to invisible in
daylight. One classic example is the particular race cars fueled by
methanol crashing with fuel fires, with most visible sign of the fire
being "heat ripples" seen where viewing conditions favor visibility of
that effect.
Propane torch flames are very faint in areas illuminated by direct
sunlight. A natural gas stove flame is dimmer than a propane torch flame,
so a similar natural gas flame in a bright sunlit environment has a fair
chance of being invisible.
Fire fighters in a hydrogen risk environment have to be extremely careful
since even the tiniest static electricity spark will ignite a leak.
Ethylene is similar in this area, and acetylene is much worse than both
ethylene and hydrogen!
Failsafe systems are designed to vent flare the hydrogen upwards in
the event of a failure - which is fine unless you have rolled the car
over. Then the flame burns whatever it touches and becomes optically
dense.
The bulk of released hydrogen, whether burning or not, will still go
upwards because hydrogen is lighter than air.
Increasing optical density of the flame means the flame changing from a
dim blue one to a more ordinary whitish-orange-yellow one that is easy to
see in daylight.
<SNIP from here to concentrate on relevance to some fire safety/hazard
issues of hydrogen>
I see the more legitimate arguments against hydrogen being on other
grounds - such as how much can be practically stored on a personal
hydrogen-fueled vehicle, and after that arguments as to fuel cells
requiring (or not necessarily requiring) expensive materials with low
available tonnage worldwide or else figure out how usefully (or not) we
can burn it in an IC engine, a steam engine, or a Stirling engine, etc.
where gasoline and diesel finds IC engines practical.
Delivering/generating hydrogen from "whatever energy source" to a fuel
pumping station (whether it's a neighborhood or town "fuel station" or a
smaller device for most homeowners having garages to have) and
compressing the hydrogen into a car's fuel tank (or otherwise storing a
useful amount into the vehicle) are also significant arguments against
mass-market hydrogen-fueled vehicles.
If it can ever be be practical to use hydrogen to fuel cars, it's not
"a tall order" to make such a thing having reasonable safety along the
lines of safety of using gasoline as a fuel for cars.
So I expect hydrogen fueled cars to not have safety issues to be the
tallest hurdles that stand in their way!
- Don Klipstein (
[email protected])