At the risk of unnecessarily confusing the situation,
One is volts divided by seconds and the other is voltage multiplied by seconds.
If you were to substitute velocity for voltage, the first would be distance and the second acceleration.
is not quite right.
If velocity = Voltage, then
Volts/Seconds = velocity/seconds = Acceleration, and
Volt*seconds =velocity*seconds = distance.
The interesting thing about this question is, where would this question specifically arise? In general it is a question about dimensional analysis, but not many people encounter Volt seconds in everyday life.