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Re: Solar-hydrogen home power system?

R

Ray Drouillard

Jan 1, 1970
0
Hatunen said:
My goal is not to feed trolls. But whenever a ceackpot manages
to sound sort of reasonable I want to make sure that readers with
a bit less sophistication about the subject are not taken in, so
we don't end up with several crackpots.

In fact, the whole hydrogen thing does sound reasonable at first
encounter. The science is sound, although the engineering is not.
And I certainly want to scotch the notion that engineering
problems can always be overcome if we are just diligent enough.
Technical problems can frequently be overcome, but engineering is
a meld of technological considerations with cost considerations.

Many things CAN be done, but it may not pay to do them.

Your last sentence is the most reasonable I have seen on this thread.

The science is sound. The engineering challenges can be overcome.
Economically, it makes little sense.


Ray
 
D

Don W.

Jan 1, 1970
0
Don Lancaster said:
On which aisle of Wal-Mart are these electrolysizers found?

Energy efficiency, of course, is ridiculously higher than fully burdened
efficiency.

--
Many thanks,

Don Lancaster
Synergetics 3860 West First Street Box 809 Thatcher, AZ 85552
voice: (928)428-4073 email: [email protected]

Please visit my GURU's LAIR web site at http://www.tinaja.com

Wal-Mart usually merchandises things that people will buy. The pdf to
which I referred discloses many reasons why hydrogen will never power very
many automobiles. The Office of Energy Efficiency and Renewable Energy is
actively promoting hydrogen research, fuel cell research and desperately
attempting to endoctrinate the general public. Fortunately, they also
publish the truth even when it hurts!

Don W.
 
G

Gymmy Bob

Jan 1, 1970
0
Sounds like a backpaddle for the "speak too soon foolish"
 
D

Don Lancaster

Jan 1, 1970
0
Terrafamilia said:
What is the current state of the art in flywheels and how much more work
is needed for home installation? One could speculate about possible
future flywheels utilizing carbon nanotubes and such. And as long as one
is speculating about possible future developments, who about using
superconductors? Operating temperatures and energy density would need to
be taken into account but that'll be part of the speculation.

Ciao,

Terrafamilia

Lithium batteries have pretty much eclipsed flywheels energy density
with far fewer hassles.
And are about to double in performance.

One major problem is that the flywheel windup motor has to be
ridiculously large if the charge time is to be faster than the discharge
time.

A second major issue involves gyro effects.

There are apparently some niche apps involving UPS power and subways,
but these certainly are not mainstream. Stationary apps would seem to be
more reasonable than moving ones. (On subways, the flywheels are
trackside, NOT on the cars).

More dollars and more manhours are being thrown at alternatives.
My feeling is that flywheel research peaked several decades ago.

See http://www.tinaja.com/glib/energfun.pdf


--
Many thanks,

Don Lancaster
Synergetics 3860 West First Street Box 809 Thatcher, AZ 85552
voice: (928)428-4073 email: [email protected]

Please visit my GURU's LAIR web site at http://www.tinaja.com
 
D

Dan Bloomquist

Jan 1, 1970
0
Ray said:
Capital cost is economics, not engineering.

Those PEM auto prototypes are running $80k+ at production levels. If we
can't afford them...
Effeciency is engineering, not economics.

If you only get 5% of the heating value of coal to the wheels of a car,
what does that fuel cost? What infrastructure? It does all count. If it
were not about cost, we could cover a little spec of desert with solar
thermal and stop using coal for electricity.
They can be related, but the person expressing that relationship needs
to be explicit.

Don's copy and paste library is a bit limited. :)
range.

Agreed.

With 65%+ efficient fuel cells, and 90%+ motors, a vehicle can turn
hydrogen into motion very efficiently. The main bugaboo is storing the
stuff (an issue that has been debated hotly in this thread).

There are now 60%+ efficient methane-fuelled fuel cells. I know of none
that are commercially available, unfortunately. If they do become
available, they would be ideal for running an ev because the methane
storage technology already exists. It still isn't as energy dense as
gasoline, but it's a lot more dense than hydrogen. It also has the safe
ty advantage of dissapating and floating away in the unlikely event of a
pressure tank rupture.

I've been an advocate of methane powered SOFC, with a possible bottom
cycle for the heat, for years. But we would have to stop wasting methane
on peakers and get Canada to expand production.
Thirdly, it's a real fuel -- not something that is derived from a fuel.
It can be mined, or very easily created from biomass.

There are no currently viable bio sources. Angiosperms and Gymnosperms
don't grow rapidly enough to be meaningful. Cultivated algae could work
in principle. But if it costs like solar...
It pretty well goes without saying that making hydrogen from grid
electricity is a no-win situation.

As far as comparing a hydrogen system to a battery system -- well, I
expect the battery system to win when you consider efficiency. The
biggest obstacle for EV transportation is the lousy range of even the
best vehicle. It would be worth it to some people to give up some
efficiency just to get more range.

I don't think 2 to 3 times the efficiency is just 'some'. So many of our
miles are just to get to work and back, short trips. Hell, if those
commuter miles where done in civics and with car pooling, it would have
a dramatic effect on our consumption.
Getting back to the original post, though -- he was talking about a
totally fixed application. The electricity --> hydrogen --> electricity
idea had occurred to me, too. I was pondering what to do with cheap
solar cells of those much-promised organic semiconductor cells become
available at a reasonable price. At the time, I lived in the city, and
was limited to the area of my (small) roof. Therefore, storage to pick
up the slack in the winter would be a necessity. Since we also had
natural gas piped in, I planned on generating any additional electricity
needed using a natural gas fuel cell. The waste heat would be used to
heat the house.

If I can someday buy a 2Kw SOFC unit for around a grand, I'd do it
without thinking because I've already run the numbers. If you bottom
SOFC into home heating, you are getting 60% high grade electrical energy
and pushing 97% overall efficiency.
Now that we live on a nice ten acre parcel, I'm not nearly so limited
when it comes to the area that I can cover with solar cells. That makes
it more feasible to get enough area covered to produce a day's worth of
electricity on even the shortest day. That cuts the storage
requirements considerably -- both in quantity and time. Hydrogen
wouldn't be necessary at all.

Of course, all of the above depends greatly upon the much-promised cheap
solar cells, as well as the availability of relatively inexpensive fuel
cells.

If you are off the grid, you will likely do what most folks I know off
the grid do. Go on an electrical energy diet while on the batteries. Use
a generator for short periods of heavy load. Use PV to supplement the
charge on your batteries. And you go on that diet because PV/batteries
means your electricity runs around $.35-$.45/kwh if you figure a twenty
year lifetime on the equipment.
Then, of course, there are things like inverters and/or DC appliances.
The ceiling fans would have to be ripped out and sold. I would also
have to find something to replace the compact fluorescent lamps that we
have used to replace almost every incandescent light in the house. I
would probably use regular red, yellow, green, and blue LEDs in fixtures
that allow the light to mix because that is more efficient than using
white LEDs (for very good quantum physics reasons).

Inverters are cheap and efficient. With CFs you don't have to live in
the dark. I've lived off grid and found kerosene lamps pleasant.
Incidentally, the cheapest way to save energy right now is to replace
all your incandescent lights with fluorescent lighting. Soon, LED
lighting will be more available.

Most of mine are CF, it is just silly to buy incandescence. $12 an eight
pack at Costco. And, modern CFs don't have a problem with the cold, they
just start a little slower.
So, my next realistic step is to make a digester to turn organic garbage
into methane. I don't expect to find an affordable methane fuel cell
any time soon, so if I get more methane than I can burn in my appliances
and vehicles, I'll use it to fuel a standard CNG generater, and use the
waste heat to heat the house. Lots of research has to be done before
getting anywhere near that far, though.



I won't argue that point. Before I buy the equipment needed to
generate, store, and use hydrogen, I will build a big water tower and
use my excess energy to pump the water uphill, and use a turbine or
water wheel to get the energy back. As a bonus, I'll also have either a
swimming pool or a fishing pond.

Check the efficiency of the system first. Remember that your electricity
is precious. Batteries may be the way to go.
I might argue with the people who are scared to death of hydrogen, or
those who say "less than zero", but I have already throught through the
hydrogen-as-a-fuel situation to have a good handle on what it would take
to make that practical. On a large scale, off-shore nuclear energy
would make it a good option. On a small scale, it would take a very
specific set of conditions to make it worthwhile.

Even if you have to put in hundreds of miles of super conduction
transmission, pumped storage would win hands down because of the loss
and capital expenditures of hydrogen.
Because it's cool?

Remember, I'm not advocating the hydrogen solution. I have thought it
through, and share the conclusion of some or the people I am arguing
with. I don't share their reasoning, however.

It is all about the numbers. If they don't add up, they don't add up.

Ray Drouillard

Best, Dan.

P.S. Get a good newsreader if you plan to spend any time on usenet.
Outlook makes a mess of the threads. I like Netscape well enough.
 
A

Anthony Matonak

Jan 1, 1970
0
Ray said:
Why are you suddenly switching from engineering to economics. Exergy,
as you defined it above, is a scientific term, and has absolutely
nothing to do with economics.

You will find that Mr. Lancaster believes that economics and
thermodynamics are not only related, but identical. Therefore
money and energy are synonymous and the words, as well as the
concepts they embrace, can be transposed or mixed at will.

For instance, since gasoline can be considered a form of stored
energy then it is also (by his definition) a form of stored
money. Therefore, you have gasoline in your bank and every time
you pay interest on your credit cards, it's costing you gallons
and gallons. Anyone who makes a profit is therefore creating
energy and, by extension, gasoline.

That fact that this is wrong will not stop him from pointing
you to his website where he explains this in great detail.

Anthony
 
D

Dan Bloomquist

Jan 1, 1970
0
Don said:
Lithium batteries have pretty much eclipsed flywheels energy density
with far fewer hassles.
And are about to double in performance.

One major problem is that the flywheel windup motor has to be
ridiculously large if the charge time is to be faster than the discharge
time.

A second major issue involves gyro effects.

There are apparently some niche apps involving UPS power and subways,
but these certainly are not mainstream. Stationary apps would seem to be
more reasonable than moving ones. (On subways, the flywheels are
trackside, NOT on the cars).

More dollars and more manhours are being thrown at alternatives.
My feeling is that flywheel research peaked several decades ago.

You have toned down your rant, but it is still a rant.

http://www.activepower.com/index.asp?pg=technology_flywheel_vs_battery

Looks like they are still in business.

What for?

Best, Dan.
 
J

Jim Logajan

Jan 1, 1970
0
Don Lancaster said:
The equivalance between dollars and energy can be observed by the
large sign out front that says UNLEADED $1.97.

I just filled up today - it cost US$2.499/gallon.
Yes, if the price of gas goes up, the exergy of hydrogen goes down.

Looks like the exergy of hydrogen is going up rather fast.

As the local cache of billions of years of stored solar energy (in the form
of hydrocarbons) is depleted, then can I expect the exergy of solar
insolation to shoot sky high?
 
J

Jim Logajan

Jan 1, 1970
0
Ray Drouillard said:
Certainly, the cost of photovoltaics makes the system uneconomical now.

It's not yet economically competitive - by about a factor of 2 or so. Small
but important distinction, IMHO.
 
J

Jim Logajan

Jan 1, 1970
0
Ray Drouillard said:
It's all an
amusing exercise for now because photovoltaics are way too expensive to
be used where grid power is cheaply available.

If you had written "...where _reliable_ grid power is...," then I would
have agreed. Where I live (Aptos - in Santa Cruz county California) grid
power is just unreliable enough that on-site power generation, even if more
expensive, is a viable option. Unreliable power can be very expensive even
when the per-kilowatthour cost is itself low.

In fact I believe many people who live in the Santa Cruz mountains own
backup generators because grid power can be out for days at a time after a
winter storm blows through. I know of some who have switched to solar
power.
 
R

Ray Drouillard

Jan 1, 1970
0
In what way? Because I don't believe that hydrogen is economically
feasible right now? If you look at the top of the thread, you'll see
that my first post said exactly that.

I may agree with the conclusion, but I see a whole lot of bad science
used to prove the point. I am trying to correct the bad science. The
biggest blooper is the one where someone equated a hydrogen chemical
explosion with an H-bomb. That was a real howler.


Ray Drouillard
 
G

Glenn Martin

Jan 1, 1970
0
Less than zero of the heating value of coal gets to the wheels of a
vehicle via hydrogen when full burden accounted for under today's
economics.
Then a car driven by hydrogen generated by electricity generated by
burning coal would run backwards?

Glenn Martin
 
R

Ray Drouillard

Jan 1, 1970
0
Dan Bloomquist said:
Those PEM auto prototypes are running $80k+ at production levels. If we
can't afford them...

True, but it still doesn't turn engineering into economics.

If you only get 5% of the heating value of coal to the wheels of a car,
what does that fuel cost? What infrastructure? It does all count. If it
were not about cost, we could cover a little spec of desert with solar
thermal and stop using coal for electricity.

Who said anything about using coal?

Even so, assuming that your statement and figures are right (they look
right), they don't indicate that engineering and economics are the same
thing.


Don's copy and paste library is a bit limited. :)


I've been an advocate of methane powered SOFC, with a possible bottom
cycle for the heat, for years. But we would have to stop wasting methane
on peakers and get Canada to expand production.

Eat more beans :)

Seriously, though, if we run out of the methane that's in the ground and
the stuff that's stuck in this methane ice stuff at the bottom of the
ocean, we can make our own by digesting biomass. Even if no cheap way
of digesting boimass on a large scale is developed, it is still
worthwhile to for some people (hobby farmers, homesteaders, people with
kudzu or water hyassin infestations) to make methane on a small scale
and use it to power their cars and homes.

We need a methane fuel cell that we can buy for a reasonable price.
After a few years, people will be buying them from the junkyards and
using them at home.

There are no currently viable bio sources. Angiosperms and Gymnosperms
don't grow rapidly enough to be meaningful. Cultivated algae could work
in principle. But if it costs like solar...

Farmers currently dump manure into a big pond and let it rot there.
There is currently some work on digesting that stuff. It isn't going to
solve the energy crisis, but it'll turn a liability into an asset for
those people.
I don't think 2 to 3 times the efficiency is just 'some'. So many of our
miles are just to get to work and back, short trips. Hell, if those
commuter miles where done in civics and with car pooling, it would have
a dramatic effect on our consumption.

We are already living with vehicles that are a whole lot less efficient
than an EV. We're doing that because EVs cost more (higher capital
costs), and EVs have a lousy range and take a long time to refuel.

If I can someday buy a 2Kw SOFC unit for around a grand, I'd do it
without thinking because I've already run the numbers. If you bottom
SOFC into home heating, you are getting 60% high grade electrical energy
and pushing 97% overall efficiency.


If you are off the grid, you will likely do what most folks I know off
the grid do. Go on an electrical energy diet while on the batteries. Use
a generator for short periods of heavy load. Use PV to supplement the
charge on your batteries. And you go on that diet because PV/batteries
means your electricity runs around $.35-$.45/kwh if you figure a twenty
year lifetime on the equipment.

We are already on an energy diet. We replaced almost all of our
incandescant lights with compact fluorescents. Still, it's not as
extreme as if we had to deal with costly photovoltaics. Even with the
low-cost photovoltaics or a methane fuel cell, I would be changing the
entire lighting system of the house over to DC-powered fluorescents,
LEDs, or electroluminescent panels. The microwave would either be
replaced with a DC model, or I would get one of those inverter
microwaves and modify the innards a bit. I would modify the computer
power supplies to run straight from the batteries. I would modify all
of my power tools that already use a DC motor, and probably grit my
teeth and use a sine wave inverter for the ones that have induction
motors. I would have to replace the ballast in the mercury lights (not
that I use them much). The furnace and pellet stove would probably no
longer be necessary.

But it wouldn't necessarily be for the money. We only spend eighty
bucks a month on electricity right now, so paying off a system that
costs more than a couple grand is going to take a few years.

Inverters are cheap and efficient. With CFs you don't have to live in
the dark. I've lived off grid and found kerosene lamps pleasant.

We used to use them at our grandparents' cottage. They are nice for
getting ready for bed, but I don't think I could read with one right
now. Mantle lanterns are every bit as bright as incandescants, though.
They're every bit as hot, too -- not too nice in the summer, but great
in the winter.
Most of mine are CF, it is just silly to buy incandescence. $12 an eight
pack at Costco. And, modern CFs don't have a problem with the cold, they
just start a little slower.

I never tried them outside.
Check the efficiency of the system first. Remember that your electricity
is precious. Batteries may be the way to go.

Just as a SWAG, a well designed water wheel should be able to hit the
low nineties. A pump should be able to hit a similar range. The motor
and generator can similarly work up in the 90s. The problem is, you
have four steps. .90 X .90 X .90 X .90 = .6561. 65% is OK for some
purposes -- like if the PV panels are cheap.
Even if you have to put in hundreds of miles of super conduction
transmission, pumped storage would win hands down because of the loss
and capital expenditures of hydrogen.

If you're talking about large-scale production, and getting the greenies
to stay off your back, you're talking about a nuke plant someplace
NIMBY -- maybe on some island somewhere. How do we then get the power
to the people? Hydrogen is one way. Superconducting cables under the
sea is another.

I'm not holding my breath.

If you're talking small-scale, then the conditions change a bit. To
make it worthwhile, you need a use for the hydrogen (like a car or
tractor), a cheap power source (geothermal, hydroelectric, magical
low-cost PV panels), and expensive alternatives.
It is all about the numbers. If they don't add up, they don't add up.



Best, Dan.

P.S. Get a good newsreader if you plan to spend any time on usenet.
Outlook makes a mess of the threads. I like Netscape well enough.

I have Mozilla, but I haven't set it up for usenet yet. The thing likes
to shut itself down at the most inopportune times, so I haven't totally
weaned myself off of OE yet.


Ray
 
R

Ray Drouillard

Jan 1, 1970
0
Jim Logajan said:
now.

It's not yet economically competitive - by about a factor of 2 or so. Small
but important distinction, IMHO.

Just let Kerry sign Kyoto and watch oil prices go up.
 
R

Ray Drouillard

Jan 1, 1970
0
Jim Logajan said:
If you had written "...where _reliable_ grid power is...," then I would
have agreed. Where I live (Aptos - in Santa Cruz county California) grid
power is just unreliable enough that on-site power generation, even if more
expensive, is a viable option. Unreliable power can be very expensive even
when the per-kilowatthour cost is itself low.

In fact I believe many people who live in the Santa Cruz mountains own
backup generators because grid power can be out for days at a time after a
winter storm blows through. I know of some who have switched to solar
power.

If I lived in California, I probably would have remembered to add
"reliable" to the sentence. Consider it added. :)


Ray Drouillard
 
G

Glenn Martin

Jan 1, 1970
0
Don Lancaster said:
Lithium batteries have pretty much eclipsed flywheels energy density
with far fewer hassles.
And are about to double in performance.

One major problem is that the flywheel windup motor has to be
ridiculously large if the charge time is to be faster than the discharge
time.

A second major issue involves gyro effects.

There are apparently some niche apps involving UPS power and subways,
but these certainly are not mainstream. Stationary apps would seem to be
more reasonable than moving ones. (On subways, the flywheels are
trackside, NOT on the cars).

More dollars and more manhours are being thrown at alternatives.
My feeling is that flywheel research peaked several decades ago.

That was clear and concise. Thanks, Don.
I've read that one of the main limitations on satellite life is the
propellant used to correct orientation. I've also read that a couple of
counter-rotating flywheels could be selectively spun down to change the
orientation of a satellite/ Also, that carbon fibre flywheels can be
engineered to last acouple of decades past the life of conventional
batteries (the second limitation on satellite life). A niche market to be
sure but one worth billions of dollars.

Glenn Martin
 
G

Glenn Martin

Jan 1, 1970
0
Don Lancaster said:
Obviously, you make a profit by paying LESS for conventional power than
you do for solar pv and similar energy sink alternates.
I apologise for the trivial nitpicking but I couldn't resist. Paying less
means that I;m taking less of a loss; not earning a profit.

Glenn Martin
 
G

Glenn Martin

Jan 1, 1970
0
Exergy is the measure of this fraction and thus the energy value. If you
can convert the present energy form into another and back again with
most of it left, you have high exergy. If not, you have low exergy or
(in the case of hydrogen) negative exergy.

How can you have negative exergy converting hydrogen to electricity?
Providing you're getting some electricity out of it, surely it has to be a
positive number.
The equivalance between dollars and energy can be observed by the large
sign out front that says UNLEADED $1.97. Ultimately all of economics is
dictated by the underlying net energy sources.

Yes, if the price of gas goes up, the exergy of hydrogen goes down.
That is the beauty of exergy. It tracks the true costs of reversible
fraction recovery.
But only in terms of gasoline. In fact the global economy uses coal and
oil for the bulk of energy production; not highly-refined gasoline.
Wouldn't a barrel of crude be a more accurate basis? Wouldn't basing you
reasoning on gasoline being the standard form of energy also bias your
reasoning against the economies of any other energy source? In 1890,
couldn't the Otto cycle engine be considered a net destroyer of coal?
Also, I know of no way to turn other forms of energy back into gasoline.
Isn't it then an extremely low exergic energy form? If exergy is important
as you say, why base economics on one of the lousiest forms of solar power
storage in existence? (millions of years to process, relatively low
returns)
Ther's also the matter of circumstances. A tank of gas in my livingroom
is useless to me. I want energy in the form of dissipated heat and light.
I might be able to convert gasoline into the same but by itself it has no
energy value to me. I would be quite willing to sacrifice gas inefficiently
to get something I can use and it would not be a bad bargain for me. The
suitability of an energy form to its' use seems to me to be as important as
the exergic value.

Glenn Martin
 
G

G. R. L. Cowan

Jan 1, 1970
0
Ray said:
OK, I have been trying to read between the lines and analyze this
statement because it keeps occurring.

Why is most of the power destroyed with electrolysis? I want some solid
engineering-type answers. I hear from other sources that the efficiency
of electrolysis is in the 75% - 90% range. That isn't bad, really.
I'll grant you that there are better ways of storing energy than
splitting water, then feeding it through a fuel cell when you need it.
Still, this "most excess power is instantly destroyed" has me
confused -- especially since it violates the laws of thermodynamics.

Also, what is exergy? In all the physics, chemistry, and thermodynamics
classes I have taken, I don't recall seeing that term. What kind of
unit does it have? Is it expressed in joules, watts, or what?

Joules. The definition I like is that exergy is energy you can use.
Sometimes it is called "availability" or available energy.

Typical chemical fuels' specific exergy typically is within a
few percentage points of their specific enthalpy of combustion.
It's even closer to their free energy of combustion.

The exergy of a quantity of heat at a given temperature
is ideally that quantity times (one minus (environment 'T'/given 'T')).


--- Graham Cowan, former hydrogen fan
http://www.eagle.ca/~gcowan/Paper_for_11th_CHC.doc --
How individual mobility gains nuclear cachet
 

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