Transistor junctions in reverse often "zener". But then they are
basically zener diodes at that point, and unlike the "real" ones,
you have to go through the transistors to find one with the voltage
you desire (and likely it won't be over a wide spread).
You have a wide variety of circuits in this 32 page application note
at differing power and simple or precision levels.
Also included are sections on how to choose resistors and capacitors.
Enjoy.