Commercial Peltier modules are built up of lots of elements, apparently
connected in series.
http://www.marlow.com/TechnicalInfo/...lectric_co.htm
which suggests that you should be able to connect several modules in
series.
If this generates more volts than you want at a lower current than you
want, you could always use a DC-to-DC converter to transform the high
voltage to a lower, or vice versa.
The Farnell catalogue lists a couple of pages of such devices -
admittedly, mostly aimed at converting 5V, 12V, 24V and 48V DC into
something in the same ballpark.
All of them use some kind of switch - these days it is usually a power
MOSFET or two - to chop the DC input to produce AC, which is then put
through a transformer to get a higher or lower AC voltage, which can
then be rectified to give the DC output you want.
This can be quite efficient - 90% or better.
There are ways of performing similar tricks with capacitors, but
transformers can shift a lot more power per unit volume.
With a bit more ingenuity you can build a circuit which can handle a
moderately wide range of input voltages - modern "universal"
switch-mode power supplies accept mains voltages from 85V rms to 265V
rms.
Your voltages sound more like the output from a solar cell, and you
might find that you could use something intended for that application.
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Bill Sloman, Nijmegen